MSDS Name:   Silicagel, functionalized, 20% Potassium permanganate
Synonym:   Potassium permanganate, solid supported on silicagel.
Company:   AboutChem.com

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7631-86-9 |Silicagel | 80 | 231-545-4 |
|----------------|--------------------------------------|----------|-----------|
| 7722-64-7 |Potassium permanganate | 20 | 231-760-3 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: O N
Risk Phrases: 8 51/53

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Contact with combustible material may cause fire. Toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment.

Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7631-86-9:
United Kingdom, WEL - TWA: 6 mg/m3 TWA (inhalable dust); 2.4 mg/m
TWA (respirable dust)
United Kingdom, WEL - STEL: 18 mg/m3 STEL (inhalable dust); 7.2 m
STEL (respirable dust)

Germany: 4 mg/m3 TWA (inhalable fraction)
Russia: 1 mg/m3 TWA
CAS# 7722-64-7:
United Kingdom, WEL - TWA: (listed as manganese, inorganic
compounds): 0.5 mg/m3 TWA
United Kingdom, WEL - STEL: (listed as manganese, inorganic
compounds): 1.5 mg/m3 STEL
United States OSHA: 5 mg/m3 Ceiling (as Mn) (listed under Mangan
compounds, n.o.s.).
Belgium - TWA: (listed as manganese compounds, n.o.s.): 0.2 mg/m3
(as Mn)
Japan: (listed as manganese compounds, n.o.s.): 0.3 mg/m3 OEL (ex
organic compounds, as Mn)
Malaysia: (listed as manganese, inorganic compounds): 0.2 mg/m3 T
(as Mn)
Netherlands: (listed as manganese compounds, n.o.s.): 3 mg/m3 STE
(as Mn)
Netherlands: (listed as manganese compounds, n.o.s.): 1 mg/m3 MAC
Mn)
Spain: (listed as manganese, inorganic compounds): 0.2 mg/m3 VLA-
(as Mn)

Personal Protective Equipment

Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Solid
Color: purple
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: soluble 20%
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials.
Incompatibilities with Other Materials:
Strong reducing agents, finely powdered metals, peroxides, zinc,
copper.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 7631-86-9: EU8655000 VV7565000
CAS# 7722-64-7: SD6475000
LD50/LC50:
CAS# 7631-86-9: Draize test, rabbit, eye: 25 mg/24H Mild.
CAS# 7722-64-7: Oral, mouse: LD50 = 2157 mg/kg; Oral, mouse: LD50 =
750 mg/kg; Oral, rat: LD50 = 750 mg/kg.
Carcinogenicity:
Silicagel -
Not listed by ACGIH, IARC, or NTP.
Potassium permanganate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****



**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: POTASSIUM PERMANGANATE, MIXTURE
Hazard Class: 5.1
UN Number: 1490
Packing Group: II
IMO
Shipping Name: POTASSIUM PERMANGANATE, MIXTURE
Hazard Class: 5.1
UN Number: 1490
Packing Group: II
RID/ADR
Shipping Name: POTASSIUM PERMANGANATE, MIXTURE
Hazard Class: 5.1
UN Number: 1490
Packing group: II
USA RQ: CAS# 7722-64-7: 100 lb final RQ; 45.4 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: O N
Risk Phrases:
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
R 8 Contact with combustible material may cause
fire.
Safety Phrases:
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7631-86-9: 0
CAS# 7722-64-7: 2
Canada
CAS# 7631-86-9 is listed on Canada's DSL List.
CAS# 7722-64-7 is listed on Canada's DSL List.
CAS# 7631-86-9 is listed on Canada's Ingredient Disclosure List.
CAS# 7722-64-7 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7631-86-9 is listed on the TSCA inventory.
CAS# 7722-64-7 is listed on the TSCA inventory.

**** SECTION 16 - ADDITIONAL INFORMATION ****

Text for R-phrases from Section 2
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.

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