MSDS Name:   Nitric acid-d, 68 wt. % solution in d2o, 99+ atom % d
Synonym:  
Company:   AboutChem.com

**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 13587-52-5 |Nitric acid-d, 68 wt. % solution in D2| | 237-024-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: C
Risk Phrases: 35

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Causes severe burns.Oxidizer.Hygroscopic (absorbs moisture from the
air).

Potential Health Effects
Eye:
Causes severe eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns. May cause perforation of the
digestive tract.
Inhalation:
May be fatal if inhaled. Effects may be delayed. May cause
irritation of the respiratory tract with burning pain in the nose and
throat, coughing, wheezing, shortness of breath and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure
may cause erosion of teeth.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting and seek IMMEDIATE MEDICAL ADVICE.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. Substance is noncombustible.
Extinguishing Media:
Do NOT use water directly on fire. Use water spray to cool
fire-exposed containers. Substance is noncombustible; use agent most
appropriate to extinguish surrounding fire.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Neutralize spill with sodium
bicarbonate. Use water spray to disperse the gas/vapor.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on
skin, or on clothing. Use only in a chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Corrosives area. Store under an
inert atmosphere.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
CAS# 13587-52-5:


Personal Protective Equipment

Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Liquid
Color: colorless
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: DNO3
Molecular Weight: 64.02

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Decomposes when in contact with air, light, or organic matter.
Conditions to Avoid:
High temperatures, incompatible materials, light, combustible
materials, organic materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Reducing agents, bases, metals.
Hazardous Decomposition Products:
Nitrogen oxides.
Hazardous Polymerization: Will not occur.

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 13587-52-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Nitric acid-d, 68 wt. % solution in D2O -
Not listed by ACGIH, IARC, or NTP.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
For nitric acid:
Mosquito fish: TLm=72 ppm/96H (fresh water) Cockle:
LC50=330-1000 ppm/48H (salt water)

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
IMO
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing Group: II
RID/ADR
Shipping Name: NITRIC ACID
Hazard Class: 8
UN Number: 2031
Packing group: II

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 13587-52-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 13587-52-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 13587-52-5 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

MSDS Creation Date: 1/18/2000 Revision #2 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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