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2-Acetoxy-3,3-dichlorotetrahydropyran 96+%



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    2008-07-10 20:15:32   MSDS    

    ****Section 1 - Chemical Product And Company Identification ****

    MSDS Name:   2-Acetoxy-3,3-dichlorotetrahydropyran 96+%
    Synonym:   3,3-Dichlorotetrahydro-2H-pyran-2-ol acetate; 3,3-Dichlorotetrahydro-2H-pyran-2-yl acetate
    Company:   AboutChem.com

    **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

    +----------------+--------------------------------------+----------+-----------+
    | CAS# | Chemical Name | % | EINECS# |
    |----------------|--------------------------------------|----------|-----------|
    +----------------+--------------------------------------+----------+-----------+
    Hazard Symbols: XI
    Risk Phrases: 36/37/38

    **** SECTION 3 - HAZARDS IDENTIFICATION ****

    EMERGENCY OVERVIEW
    Irritating to eyes, respiratory system and skin.The toxicological
    properties of this material have not been fully
    investigated.Moisture sensitive.

    Potential Health Effects
    Eye:
    Causes eye irritation.
    Skin:
    Causes skin irritation.
    Ingestion:
    Causes gastrointestinal irritation with nausea, vomiting and
    diarrhea.
    Inhalation:
    Causes respiratory tract irritation.
    Chronic:
    No information found.

    **** SECTION 4 - FIRST AID MEASURES ****

    Eyes:
    Immediately flush eyes with plenty of water for at least 15 minutes,
    occasionally lifting the upper and lower eyelids. Get medical aid
    immediately.
    Skin:
    Get medical aid. Flush skin with plenty of water for at least 15
    minutes while removing contaminated clothing and shoes.
    Ingestion:
    Do not induce vomiting. If victim is conscious and alert, give 2-4
    cupfuls of milk or water. Never give anything by mouth to an
    unconscious person. Get medical aid. Do NOT induce vomiting. If
    conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or
    water.
    Inhalation:
    Remove from exposure and move to fresh air immediately. If not
    breathing, give artificial respiration. If breathing is difficult,
    give oxygen. Get medical aid.
    Notes to Physician:

    **** SECTION 5 - FIRE FIGHTING MEASURES ****

    General Information:
    As in any fire, wear a self-contained breathing apparatus in
    pressure-demand, MSHA/NIOSH (approved or equivalent), and full
    protective gear. During a fire, irritating and highly toxic gases
    may be generated by thermal decomposition or combustion.
    Extinguishing Media:
    In case of fire, use water, dry chemical, chemical foam, or
    alcohol-resistant foam.

    **** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

    General Information: Use proper personal protective equipment as indicated
    in Section 8.
    Spills/Leaks:
    Absorb spill with inert material (e.g. vermiculite, sand or earth),
    then place in suitable container. Clean up spills immediately,
    observing precautions in the Protective Equipment section.

    **** SECTION 7 - HANDLING and STORAGE ****

    Handling:
    Wash thoroughly after handling. Remove contaminated clothing and
    wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid
    ingestion and inhalation.
    Storage:
    Store in a cool, dry place. Keep container closed when not in use.

    **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

    Engineering Controls:
    Use adequate general or local exhaust ventilation to keep airborne
    concentrations below the permissible exposure limits.
    Exposure Limits

    Personal Protective Equipment

    Eyes:
    Wear appropriate protective eyeglasses or chemical
    safety goggles as described by OSHA's eye and face
    protection regulations in 29 CFR 1910.133 or European
    Standard EN166.
    Skin:
    Wear appropriate protective gloves and clothing to
    prevent skin exposure.
    Clothing:
    Wear appropriate protective clothing to minimize
    contact with skin.
    Respirators:
    Follow the OSHA respirator regulations found in 29
    CFR 1910.134 or European Standard EN 149. Use a
    NIOSH/MSHA or European Standard EN 149 approved
    respirator if exposure limits are exceeded or if
    irritation or other symptoms are experienced.

    **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

    Physical State: Liquid
    Color: clear, colorless
    Odor: Not available.
    pH: Not available.
    Vapor Pressure: Not available.
    Viscosity: Not available.
    Boiling Point: @ 11.00mmHg
    Freezing/Melting Point: Not available.
    Autoignition Temperature: Not available.
    Flash Point: Not available.
    Explosion Limits, lower: Not available.
    Explosion Limits, upper: Not available.
    Decomposition Temperature: >200 deg C
    Solubility in water:
    Specific Gravity/Density:
    Molecular Formula: C7H10Cl2O3
    Molecular Weight: 213.06

    **** SECTION 10 - STABILITY AND REACTIVITY ****

    Chemical Stability:
    Stable under normal temperatures and pressures.
    Conditions to Avoid:
    Incompatible materials, moisture.
    Incompatibilities with Other Materials:
    Strong oxidants.
    Hazardous Decomposition Products:
    Hydrogen chloride, carbon monoxide, irritating and toxic fumes and
    gases, carbon dioxide.
    Hazardous Polymerization: Has not been reported.

    **** SECTION 11 - TOXICOLOGICAL INFORMATION ****

    RTECS#:
    No CAS#s in product.
    LD50/LC50:
    Carcinogenicity:

    **** SECTION 12 - ECOLOGICAL INFORMATION ****



    **** SECTION 13 - DISPOSAL CONSIDERATIONS ****

    Dispose of in a manner consistent with federal, state, and local regulations.

    **** SECTION 14 - TRANSPORT INFORMATION ****

    IATA
    Not regulated as a hazardous material.
    IMO
    Not regulated as a hazardous material.
    RID/ADR
    Not regulated as a hazardous material.

    **** SECTION 15 - REGULATORY INFORMATION ****

    European/International Regulations
    European Labeling in Accordance with EC Directives
    Hazard Symbols: XI
    Risk Phrases:
    R 36/37/38 Irritating to eyes, respiratory system
    and skin.
    Safety Phrases:
    S 24/25 Avoid contact with skin and eyes.
    WGK (Water Danger/Protection)
    Canada
    None of the chemicals in this product are listed on the DSL/NDSL list.
    US FEDERAL
    TSCA

    **** SECTION 16 - ADDITIONAL INFORMATION ****

    MSDS Creation Date: 9/02/1997 Revision #2 Date: 3/18/2003

    The information above is believed to be accurate and represents the best
    information currently available to us. However, we make no warranty of
    merchantability or any other warranty, express or implied, with respect to
    such information, and we assume no liability resulting from its use. Users
    should make their own investigations to determine the suitability of the
    information for their particular purposes. In no way shall the company be
    liable for any claims, losses, or damages of any third party or for lost
    profits or any special, indirect, incidental, consequential or exemplary
    damages, howsoever arising, even if the company has been advised of
    the possibility of such damages.
    --------------------------------------------------------------------------------
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