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1-Aziridineethanol, 97%



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  •   

    2008-07-10 21:28:43   MSDS    

    ****Section 1 - Chemical Product And Company Identification ****

    MSDS Name:   1-Aziridineethanol, 97%
    Synonym:   2-(1-Aziridinyl)ethanol; Beta-Hydroxy-1-Ethylaziridine; 2-Hydroxy-1-Ethylaziridine; N-(Beta-Hydroxyethyl)aziridine.
    Company:   AboutChem.com

    **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

    +----------------+--------------------------------------+----------+-----------+
    | CAS# | Chemical Name | % | EINECS# |
    |----------------|--------------------------------------|----------|-----------|
    | 1072-52-2 |1-Aziridineethanol | 97 | 214-009-4 |
    +----------------+--------------------------------------+----------+-----------+
    Hazard Symbols: T
    Risk Phrases: 23/24/25 33

    **** SECTION 3 - HAZARDS IDENTIFICATION ****

    EMERGENCY OVERVIEW
    Toxic by inhalation, in contact with skin and if swallowed. Danger
    of cumulative effects.Toxic.

    Potential Health Effects
    Eye:
    Causes eye irritation. May cause chemical conjunctivitis and
    corneal damage.
    Skin:
    Causes skin irritation. Harmful if absorbed through the skin. May
    cause irritation and dermatitis. May cause cyanosis of the
    extremities.
    Ingestion:
    Harmful if swallowed. May cause gastrointestinal irritation with
    nausea, vomiting and diarrhea.
    Inhalation:
    May cause respiratory tract irritation. Aspiration may lead to
    pulmonary edema. Can produce delayed pulmonary edema. Inhalation at
    high concentrations may cause CNS depression and asphixiation.
    Chronic:
    Effects may be delayed.

    **** SECTION 4 - FIRST AID MEASURES ****

    Eyes:
    Immediately flush eyes with plenty of water for at least 15 minutes,
    occasionally lifting the upper and lower eyelids. Get medical aid.
    Skin:
    Get medical aid. Flush skin with plenty of water for at least 15
    minutes while removing contaminated clothing and shoes. Wash clothing
    before reuse.
    Ingestion:
    Get medical aid. Do NOT induce vomiting. If conscious and alert,
    rinse mouth and drink 2-4 cupfuls of milk or water.
    Inhalation:
    Remove from exposure and move to fresh air immediately. If not
    breathing, give artificial respiration. If breathing is difficult,
    give oxygen. Get medical aid.
    Notes to Physician:
    Treat symptomatically and supportively.

    **** SECTION 5 - FIRE FIGHTING MEASURES ****

    General Information:
    As in any fire, wear a self-contained breathing apparatus in
    pressure-demand, MSHA/NIOSH (approved or equivalent), and full
    protective gear. During a fire, irritating and highly toxic gases
    may be generated by thermal decomposition or combustion. Use water
    spray to keep fire-exposed containers cool. Combustible liquid.
    Vapors may be heavier than air. They can spread along the ground and
    collect in low or confined areas. Containers may explode when heated.
    Extinguishing Media:
    Use agent most appropriate to extinguish fire. Use water spray, dry
    chemical, carbon dioxide, or appropriate foam.

    **** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

    General Information: Use proper personal protective equipment as indicated
    in Section 8.
    Spills/Leaks:
    Absorb spill with inert material (e.g. vermiculite, sand or earth),
    then place in suitable container. Avoid runoff into storm sewers and
    ditches which lead to waterways. Clean up spills immediately,
    observing precautions in the Protective Equipment section. Remove all
    sources of ignition. Use a spark-proof tool. Provide ventilation.

    **** SECTION 7 - HANDLING and STORAGE ****

    Handling:
    Wash thoroughly after handling. Avoid contact with eyes, skin, and
    clothing. Empty containers retain product residue, (liquid and/or
    vapor), and can be dangerous. Keep container tightly closed. Keep
    away from heat, sparks and flame. Avoid ingestion and inhalation. Use
    with adequate ventilation. Wash clothing before reuse. Do not
    pressurize, cut, weld, braze, solder, drill, grind, or expose empty
    containers to heat, sparks or open flames.
    Storage:
    Keep away from heat, sparks, and flame. Keep away from sources of
    ignition. Store in a tightly closed container. Store in a cool, dry,
    well-ventilated area away from incompatible substances.

    **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

    Engineering Controls:
    Facilities storing or utilizing this material should be equipped
    with an eyewash facility and a safety shower. Use adequate
    ventilation to keep airborne concentrations low.
    Exposure Limits
    CAS# 1072-52-2:


    Personal Protective Equipment

    Eyes:
    Wear appropriate protective eyeglasses or chemical
    safety goggles as described by OSHA's eye and face
    protection regulations in 29 CFR 1910.133 or European
    Standard EN166.
    Skin:
    Wear appropriate protective gloves to prevent skin
    exposure.
    Clothing:
    Wear appropriate protective clothing to prevent skin
    exposure.
    Respirators:
    A respiratory protection program that meets OSHA's 29
    CFR 1910.134 and ANSI Z88.2 requirements or European
    Standard EN 149 must be followed whenever workplace
    conditions warrant respirator use.

    **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

    Physical State: Liquid
    Color: colorless
    Odor: alcohol-like
    pH: Not available.
    Vapor Pressure: Not available.
    Viscosity: Not available.
    Boiling Point: 167.9 deg C @ 760.00mm Hg
    Freezing/Melting Point: Not available.
    Autoignition Temperature: 334 deg C ( 633.20 deg F)
    Flash Point: 67 deg C ( 152.60 deg F)
    Explosion Limits, lower: 1.8%
    Explosion Limits, upper: Not available.
    Decomposition Temperature:
    Solubility in water:
    Specific Gravity/Density: 1.0880g/cm3
    Molecular Formula: C4H9NO
    Molecular Weight: 87.12

    **** SECTION 10 - STABILITY AND REACTIVITY ****

    Chemical Stability:
    Stable at room temperature in closed containers under normal storage
    and handling conditions.
    Conditions to Avoid:
    Incompatible materials, ignition sources, excess heat.
    Incompatibilities with Other Materials:
    Acid chlorides, acid anhydrides, strong acids, strong oxidizing
    agents.
    Hazardous Decomposition Products:
    Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and
    gases, carbon dioxide.
    Hazardous Polymerization: Has not been reported

    **** SECTION 11 - TOXICOLOGICAL INFORMATION ****

    RTECS#:
    CAS# 1072-52-2: CM7000000
    LD50/LC50:
    CAS# 1072-52-2: Draize test, rabbit, eye: 100 uL/24H Severe; Draize
    test, rabbit, skin: 500 uL/24H Severe; Oral, rat: LD50 = 74 mg/kg;
    Skin, rabbit: LD50 = 71 uL/kg.
    Carcinogenicity:
    1-Aziridineethanol -
    Not listed by ACGIH, IARC, or NTP.
    Other:
    See actual entry in RTECS for complete information.

    **** SECTION 12 - ECOLOGICAL INFORMATION ****



    **** SECTION 13 - DISPOSAL CONSIDERATIONS ****

    Dispose of in a manner consistent with federal, state, and local regulations.

    **** SECTION 14 - TRANSPORT INFORMATION ****

    IATA
    Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
    Hazard Class: 6.1
    UN Number: 2810
    Packing Group: II
    IMO
    Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
    Hazard Class: 6.1
    UN Number: 2810
    Packing Group: II
    RID/ADR
    Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
    Hazard Class: 6.1
    UN Number: 2810
    Packing group: II

    **** SECTION 15 - REGULATORY INFORMATION ****

    European/International Regulations
    European Labeling in Accordance with EC Directives
    Hazard Symbols: T
    Risk Phrases:
    R 23/24/25 Toxic by inhalation, in contact with skin
    and if swallowed.
    R 33 Danger of cumulative effects.
    Safety Phrases:
    S 23 Do not inhale gas/fumes/vapour/spray.
    S 24/25 Avoid contact with skin and eyes.
    S 28A After contact with skin, wash immediately with
    plenty of water.
    S 37 Wear suitable gloves.
    S 45 In case of accident or if you feel unwell, seek
    medical advice immediately (show the label where
    possible).
    WGK (Water Danger/Protection)
    CAS# 1072-52-2: No information available.
    Canada
    CAS# 1072-52-2 is listed on Canada's DSL List.
    CAS# 1072-52-2 is listed on Canada's Ingredient Disclosure List.
    US FEDERAL
    TSCA
    CAS# 1072-52-2 is listed on the TSCA inventory.

    **** SECTION 16 - ADDITIONAL INFORMATION ****

    MSDS Creation Date: 8/02/1999 Revision #2 Date: 3/18/2003

    The information above is believed to be accurate and represents the best
    information currently available to us. However, we make no warranty of
    merchantability or any other warranty, express or implied, with respect to
    such information, and we assume no liability resulting from its use. Users
    should make their own investigations to determine the suitability of the
    information for their particular purposes. In no way shall the company be
    liable for any claims, losses, or damages of any third party or for lost
    profits or any special, indirect, incidental, consequential or exemplary
    damages, howsoever arising, even if the company has been advised of
    the possibility of such damages.
    --------------------------------------------------------------------------------
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