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Cadmium chloride, anhydrous, 99%



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    2008-07-10 22:00:47   MSDS    

    ****Section 1 - Chemical Product And Company Identification ****

    MSDS Name:   Cadmium chloride, anhydrous, 99%
    Synonym:   Cadmium dichloride.
    Company:   AboutChem.com

    **** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

    +----------------+--------------------------------------+----------+-----------+
    | CAS# | Chemical Name | % | EINECS# |
    |----------------|--------------------------------------|----------|-----------|
    | 10108-64-2 |Cadmium chloride | >99 | 233-296-7
    +----------------+--------------------------------------+----------+-----------+
    Hazard Symbols: T+ N
    Risk Phrases: 25 26 45 46 48/23/25 60 61 50/53

    **** SECTION 3 - HAZARDS IDENTIFICATION ****

    EMERGENCY OVERVIEW
    Toxic if swallowed. Very toxic by inhalation. May cause cancer. May
    cause heritable genetic damage. Toxic : danger of serious damage to
    health by prolonged exposure through inhalation and if swallowed.
    May impair fertility. May cause harm to the unborn child. Very toxic
    to aquatic organisms; may cause long-term adverse effects in the
    aquatic environment.Hygroscopic.

    Potential Health Effects
    Eye:
    May cause eye irritation. Exposure to the substance as an aqueous
    solution may cause irritation and corneal abnormalities.
    Skin:
    May cause skin irritation. May be absorbed through the skin in
    harmful amounts.
    Ingestion:
    May cause gastrointestinal irritation with nausea, vomiting and
    diarrhea. Exposure may cause severe swelling of face and neck areas
    with possible death.
    Inhalation:
    May be fatal if inhaled. Irritation may lead to chemical pneumonitis
    and pulmonary edema. May cause ulceration and perforation of the
    nasal septum if inhaled in excessive quantities.
    Chronic:
    May cause respiratory tract cancer. Prolonged or repeated exposure
    may cause permanent bone structure abnormalities. Chronic inhalation
    may cause nasal septum ulceration and perforation. Chronic
    inhalation of cadmium compounds has been associated with lung and
    prostate cancer. The primary target organ for chronic cadmium disease
    is clearly the kidney. An inhalation study of cadmium chloride in
    rats exposed 23 hrs/day for 18 mo at 12.5, 25 or 50 ug/m3, as Cd,
    produced a frequency of primary lung carcinomas of 15.4%, 52.6% and
    71.4%, respectively. There were no primary lung carcinomas in the
    controls.

    **** SECTION 4 - FIRST AID MEASURES ****

    Eyes:
    In case of contact, immediately flush eyes with plenty of water for
    at least 15 minutes. Get medical aid.
    Skin:
    In case of contact, flush skin with plenty of water. Remove
    contaminated clothing and shoes. Get medical aid if irritation
    develops and persists. Wash clothing before reuse.
    Ingestion:
    If swallowed, do not induce vomiting unless directed to do so by
    medical personnel. Never give anything by mouth to an unconscious
    person. Get medical aid.
    Inhalation:
    Poison material. If inhaled, get medical aid immediately. Remove
    victim to fresh air. If not breathing, give artificial respiration.
    If breathing is difficult, give oxygen.
    Notes to Physician:
    Antidote:
    The use of Calcium disodium EDTA as a chelating agent should be
    determined by qualified medical personnel.

    **** SECTION 5 - FIRE FIGHTING MEASURES ****

    General Information:
    As in any fire, wear a self-contained breathing apparatus in
    pressure-demand, MSHA/NIOSH (approved or equivalent), and full
    protective gear. Water runoff can cause environmental damage. Dike
    and collect water used to fight fire. Non-combustible, substance
    itself does not burn but may decompose upon heating to produce
    corrosive and/or toxic fumes.
    Extinguishing Media:
    Use extinguishing media most appropriate for the surrounding fire.

    **** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

    General Information: Use proper personal protective equipment as indicated
    in Section 8.
    Spills/Leaks:
    Vacuum or sweep up material and place into a suitable disposal
    container. Avoid runoff into storm sewers and ditches which lead to
    waterways. Clean up spills immediately, observing precautions in the
    Protective Equipment section. Wear a self contained breathing
    apparatus and appropriate Personal protection. (See Exposure
    Controls, Personal Protection section). Avoid generating dusty
    conditions. Provide ventilation.

    **** SECTION 7 - HANDLING and STORAGE ****

    Handling:
    Wash thoroughly after handling. Remove contaminated clothing and
    wash before reuse. Minimize dust generation and accumulation. Do not
    get in eyes, on skin, or on clothing. Do not breathe dust. Use only
    with adequate ventilation.
    Storage:
    Do not store in direct sunlight. Store in a tightly closed
    container. Store in a cool, dry, well-ventilated area away from
    incompatible substances.

    **** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

    Engineering Controls:
    Use process enclosure, local exhaust ventilation, or other
    engineering controls to control airborne levels below recommended
    exposure limits. Facilities storing or utilizing this material should
    be equipped with an eyewash facility and a safety shower. Use
    substance with extreme caution and designate regulated areas for use.
    Personal Protective Equipment

    Eyes:
    Wear appropriate protective eyeglasses or chemical
    safety goggles as described by OSHA's eye and face
    protection regulations in 29 CFR 1910.133 or European
    Standard EN166.
    Skin:
    Wear impervious gloves.
    Clothing:
    Wear appropriate protective clothing to prevent skin
    exposure.
    Respirators:
    Follow the OSHA respirator regulations found in 29
    CFR 1910.134 or European Standard EN 149. Always use
    a NIOSH or European Standard EN 149 approved
    respirator when necessary.

    **** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

    Physical State: Crystals
    Color: white
    Odor: odorless
    pH: Not available.
    Vapor Pressure: 10 mm Hg @ 656 deg C
    Viscosity: Not available.
    Boiling Point: 960 deg C @ 760 mm Hg
    Freezing/Melting Point: 568 deg C
    Autoignition Temperature: Not applicable.
    Flash Point: Not applicable.
    Explosion Limits, lower: Not available.
    Explosion Limits, upper: Not available.
    Decomposition Temperature:
    Solubility in water: 1400 g/L (20C)
    Specific Gravity/Density: 4.05 g/cm3 @ 25C
    Molecular Formula: CdCl2
    Molecular Weight: 183.316

    **** SECTION 10 - STABILITY AND REACTIVITY ****

    Chemical Stability:
    Stable at room temperature in closed containers under normal storage
    and handling conditions.
    Conditions to Avoid:
    Dust generation, excess heat.
    Incompatibilities with Other Materials:
    Strong oxidizing agents, bromine trifluoride, sulfur, potassium,
    selenium, tellurium, hydrogen azide.
    Hazardous Decomposition Products:
    Irritating and toxic fumes and gases, cadmium fumes, chloride fumes,
    toxic cadmium oxide fumes.
    Hazardous Polymerization: Will not occur.

    **** SECTION 11 - TOXICOLOGICAL INFORMATION ****

    RTECS#:
    CAS# 10108-64-2: EV0175000
    LD50/LC50:
    CAS# 10108-64-2: Oral, mouse: LD50 = 60 mg/kg; Oral, mouse: LD50 =
    3.3 mg/kg; Oral, rat: LD50 = 88 mg/kg.
    Carcinogenicity:
    Cadmium chloride -
    Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
    Other:
    See actual entry in RTECS for complete information.

    **** SECTION 12 - ECOLOGICAL INFORMATION ****

    Ecotoxicity:
    Fish: Bluegill/Sunfish: 1.94ppm; 96HJapanese quail, oral LC50=2584
    ppm/5D
    Ring-necked pheasant, oral LC50=767 ppm/5D

    **** SECTION 13 - DISPOSAL CONSIDERATIONS ****

    Dispose of in a manner consistent with federal, state, and local regulations.

    **** SECTION 14 - TRANSPORT INFORMATION ****

    IATA
    Shipping Name: CADMIUM COMPOUND
    Hazard Class: 6.1
    UN Number: 2570
    Packing Group: I
    IMO
    Shipping Name: CADMIUM COMPOUND
    Hazard Class: 6.1
    UN Number: 2570
    Packing Group: I
    RID/ADR
    Shipping Name: CADMIUM COMPOUND
    Hazard Class: 6.1
    UN Number: 2570
    Packing group: III

    **** SECTION 15 - REGULATORY INFORMATION ****

    European/International Regulations
    European Labeling in Accordance with EC Directives
    Hazard Symbols: T+ N
    Risk Phrases:
    R 25 Toxic if swallowed.
    R 26 Very toxic by inhalation.
    R 45 May cause cancer.
    R 46 May cause heritable genetic damage.
    R 48/23/25 Toxic : danger of serious damage to
    health by prolonged exposure through inhalation and if
    swallowed.
    R 60 May impair fertility.
    R 61 May cause harm to the unborn child.
    R 50/53 Very toxic to aquatic organisms; may cause
    long-term adverse effects in the aquatic environment.
    Safety Phrases:
    S 53 Avoid exposure - obtain special instructions
    before use.
    S 45 In case of accident or if you feel unwell, seek
    medical advice immediately (show the label where
    possible).
    S 60 This material and/or its container must be
    disposed of as hazardous waste.
    S 61 Avoid release to the environment. Refer to
    special instructions/Safety data sheets.
    WGK (Water Danger/Protection)
    CAS# 10108-64-2: No information available.
    United Kingdom Occupational Exposure Limits

    United Kingdom Maximum Exposure Limits

    Canada
    None of the chemicals in this product are listed on the DSL/NDSL list.
    CAS# 10108-64-2 is not listed on Canada's Ingredient Disclosure List.
    Exposure Limits
    CAS# 10108-64-2: OEL-ARAB Republic of Egypt:TWA 0.05 mg(Cd)/m3
    OEL-AUSTRALIA:TWA 0.05 mg(Cd)/m3
    OEL-BELGIUM:TWA 0.05 mg(Cd)/m3
    OEL-CZECHOSLOVAKIA:TWA 0.05 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
    OEL-DENMARK:TWA 0.01 mg(Cd)/m3
    OEL-FINLAND:TWA 0.02 mg(Cd)/m3;Carcinogen
    OEL-FRANCE;Skin
    OEL-GERMANY;Carcinogen
    OEL-INDIA:TWA 0.05 mg(Cd)/m3
    OEL-JAPAN:TWA 0.05 mg(Cd)/m3
    OEL-THE NETHERLANDS:TWA 0.02 mg(Cd)/m3;STEL 0.1 mg(Cd)/m3
    OEL-THE PHILIPPINES:TWA 0.2 mg(Cd)/m3
    OEL-RUSSIA:TWA 0.01 mg(Cd)/m3;STEL 0.05 mg(Cd)/m3
    OEL-SWEDEN:TWA 0.02 mg(Cd)/m3;Carcinogen
    OEL-SWITZERLAND:TWA 0.05 mg(Cd)/m3
    OEL-SWITZERLAND;Carcinogen
    OEL-THAILAND:TWA 0.2 mg(Cd)/m3;STEL 0.5 mg(Cd)/m3
    OEL-TURKEY:TWA 0.2 mg(Cd)/m3
    OEL-UNITED KINGDOM:TWA 0.01 mg(Cd)/m3
    OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
    OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
    US FEDERAL
    TSCA
    CAS# 10108-64-2 is not listed on the TSCA inventory.
    It is for research and development use only.

    **** SECTION 16 - ADDITIONAL INFORMATION ****

    MSDS Creation Date: 6/08/1999 Revision #2 Date: 11/21/2002

    The information above is believed to be accurate and represents the best
    information currently available to us. However, we make no warranty of
    merchantability or any other warranty, express or implied, with respect to
    such information, and we assume no liability resulting from its use. Users
    should make their own investigations to determine the suitability of the
    information for their particular purposes. In no way shall the company be
    liable for any claims, losses, or damages of any third party or for lost
    profits or any special, indirect, incidental, consequential or exemplary
    damages, howsoever arising, even if the company has been advised of
    the possibility of such damages.
    --------------------------------------------------------------------------------
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